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[¹«±âÈÇнÇÇè] Spectral Interpretation of Vanadium Complexes °á°úº¸°í¼ / 1. ½ÇÇè Á¦¸ñ Spectral Interpretation of Vanadium Complexes 2. ½ÇÇè°á°ú 1) ¹Ù³ªµã Âø¹° »ö 2) UV ½ºÆåÆ®·³ ±×·¡ÇÁ¿Í °¢ ÇÇÅ©ÀÇ xÃà À§Ä¡ 3) [V(H2O)6]3+ ÀÇ UV ±×·¡ÇÁ °ªÀ» ÀÌ¿ëÇÏ¿© Tanabe Sugano Diagram¿¡ ´ëÀÔÇØ, B°ª°ú ¡â_O°ª °è»ê 4) [VO(acac)2]ÀÇ ÇÇÅ©°¡ ³ªÅ¸³ª´Â ÀÌÀ¯ 3. °íÂû Âü°í¹®¡¦ |
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[¹«±âÈÇнÇÇè] Spectral Interpretation of Vanadium Complexes ¿¹ºñº¸°í¼ / 1. ½ÇÇèÁ¦¸ñ 2. ½ÇÇè¸ñÀû 3. ½ÇÇèÀÌ·Ð 4. ½Ã¾à ¹× ±â±¸ 5. ½ÇÇè¹æ¹ý / 1. ½ÇÇèÁ¦¸ñ ½ÇÇè Á¦¸ñÀº ¡®Spectral Interpretation of Vanadium Complexes¡¯ÀÌ´Ù. ÀÌ ½ÇÇèÀº ¹ÝÀÀ¼º ±Ý¼Ó ÀÌ¿ÂÀ¸·Î ³Î¸® ¿¬±¸µÇ°í ÀÖ´Â ¹Ù³ªµã(V) º¹ÇÕüÀÇ ½ºÆåÆ®·³À» Çؼ®ÇÏ¿© À̵éÀÇ ÈÇÐÀû ¼ºÁú°ú ±¸Á¶¸¦ ÀÌÇØÇϱâ À§ÇÑ ¸ñ¡¦ |
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Spectral Interpretation of Vanadium Complexes (Orgel and TanabeTsugano diagram) ¿¹ºñº¸°í¼ / 1. ½ÇÇè¸ñÇ¥ 2. ÀÌ·Ð 3. ½ÇÇè¹æ¹ý / 1. ½ÇÇè¸ñÇ¥ ½ÇÇè ¸ñÇ¥´Â ¹Ù³ªµã º¹ÇÕüÀÇ ½ºÆåÆ®·³ Çؼ®À» ÅëÇØ ÀÌµé º¹ÇÕüÀÇ ÀüÀÚ ±¸Á¶ ¹× ¹°¸®ÈÇÐÀû Ư¼ºÀ» ÀÌÇØÇÏ´Â °ÍÀÌ´Ù. ¹Ù³ªµãÀº d-ºí·Ï ÀüÀÌ ±Ý¼ÓÀ¸·Î, ´Ù¾çÇÑ »êÈ »óŸ¦ °¡Áö¸ç º¹ÀâÇÑ ÀüÀÚ ¹è¿À» º¸ÀδÙ. ÀÌ·Î ÀÎÇØ ¹Ù³ªµã º¹ÇÕ¡¦ |
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Spectral interpretation of Vanadium complexes / 1) Vanadium 2) Term symbol 3) Correlation diagrams 4) Tanabe-Sugano diagrams 5) Selection rule 6) Jahn-Teller distortion 4. ½Ã¾à ¹× ±â±¸ 1) Stock solution 2) Synthesis of [V(H2 O)6]^2+ 3) Synthesis of [V(H2 O)6]3+ 4) Synthesis of [VO(acac)2] 5. ½ÇÇè ¹æ¹ý 1) Stock solution 2) Synthesis of [VO(H2 O)5]2+ 3) S¡¦ |
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Spectral interpretation of vanadium complexes (Tanabe-Sugano diagram) ½ÇÇ躸°í¼ / 1.½ÇÇè Á¦¸ñ 2.½ÇÇè ¸ñÀû 3.½ÇÇè ÀÌ·Ð 1)VanadiumÀÇ »êÈ»óÅ 2)Hexaaquavanadium(3) -`Æȸéü d2±Ý¼Ó Âø¹° 3)Determining the ground state 4)Tanabe-sugano diagrams 5)¼±Åà ±ÔÄ¢ (selection rule) 6)Æļö 7)Tanabe-sugano±×·¡ÇÁÀÇ Çؼ® 8)Jahn-teller distortion 4.½Ã¾à ¹× ±â±¸ ¡¦ |
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ÀÚ±â»ó°üÇÔ¼ö´Â ¾î´À ½Ã°£¿¡¼ ³ªÅ¸³ ·£´ý º¯¼öÀÇ °ªÀÌ ´Ù¸¥ ½Ã°£¿¡¼ ³ªÅ¸³ °ª¿¡ ¾î¶² ÀÇÁ¸¼º(¿µÇ⼺, ¿¬°ü¼º)ÀÌ ÀÖ´ÂÁö¸¦ ¾Ë·Á ÁÖ´Â ÇÔ¼öÀÌ´Ù. ÀÌ°ÍÀº ½Ã°£ ¿µ¿ª¿¡¼ ·£´ý º¯¼öÀÇ Æ¯¼ºÀ» º¸¿©ÁÖ´Â ¹Ý¸é, ÆÄ¿ö ½ºÆåÆ®·³ ¹Ðµµ(PSD, Power spectral density) ÇÔ¼ö´Â ÁÖÆļö ¿µ¿ª¿¡¼ À¯»çÇÑ Á¤º¸¸¦ Á¦°øÇÑ´Ù. / ÆÄ¿ö ½ºÆåÆ®·³ ¹Ðµµ(Power spectral density) - Á¤ÀÇ ¼³¸í - Ư¼º ¼³¸í / ¡¦ |
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Spectral interpretation of vanadium complexes (Tanabe-Sugano diagram) ½ÇÇ躸°í¼ / 1.½ÇÇè Á¦¸ñ 2.½ÇÇè ¸ñÀû 3.½ÇÇè ÀÌ·Ð 1)VanadiumÀÇ »êÈ»óÅ 2)Hexaaquavanadium(3) -`Æȸéü d2±Ý¼Ó Âø¹° 3)Determining the ground state 4)Tanabe-sugano diagrams 5)¼±Åà ±ÔÄ¢ (selection rule) 6)Æļö 7)Tanabe-sugano±×·¡ÇÁÀÇ Çؼ® 8)Jahn-teller distortion 4.½Ã¾à ¹× ±â±¸ ¡¦ |
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Áøµ¿ ½ÅÈ£ÀÇ ½Ã°£ ¹× ÁÖÆļö ¿µ¿ª Çؼ®, Auto-correlation°ú Spectral density ¸¸Á¡ ·¹Æ÷Æ® / 1. ¼·Ð 2. ÀÌ·Ð 3. ½ÇÇè ¹æ¹ý 4. ½ÇÇè °á°ú 5. °íÂû 6. °á·Ð 7. Âü°í¹®Çå / 1. ¼·Ð Áøµ¿ ½ÅÈ£ÀÇ ½Ã°£ ¹× ÁÖÆļö ¿µ¿ª Çؼ®Àº °øÇÐ ¹× ÀÚ¿¬ °úÇÐ ºÐ¾ß¿¡¼ Áß¿äÇÑ ÁÖÁ¦ÀÌ´Ù. ÀÌ·¯ÇÑ Çؼ®Àº ½Ã½ºÅÛÀÇ µ¿ÀÛÀ» ÀÌÇØÇϰųª Áø´ÜÀ» ¼öÇàÇÏ´Â µ¥ ÇʼöÀûÀÌ´Ù. Áøµ¿ ½ÅÈ£´Â ÁÖ·Î ¼¾¼³ª ÃøÁ¤¡¦ |
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Áøµ¿ ½ÅÈ£ÀÇ ½Ã°£ ¹× ÁÖÆļö ¿µ¿ª Çؼ®, Auto-correlation°ú spectral density / 1. ¼·Ð 2. ÀÌ·Ð 3. ½ÇÇè ¹æ¹ý 4. ½ÇÇè °á°ú 5. °íÂû 6. °á·Ð 7. Âü°í¹®Çå / 1. ¼·Ð Áøµ¿ ½ÅÈ£ÀÇ ½Ã°£ ¹× ÁÖÆļö ¿µ¿ª Çؼ®Àº ±â°è°øÇÐ, ÀüÀÚ°øÇÐ ¹× ½ÅÈ£ ó¸® ºÐ¾ß¿¡¼ Áß¿äÇÑ ¿ªÇÒÀ» ÇÑ´Ù. ÀÌ·¯ÇÑ Çؼ®Àº ½Ã½ºÅÛÀÇ µ¿ÀÛÀ̳ª »óŸ¦ ÀÌÇØÇÏ°í, ½ÅÈ£ÀÇ Æ¯¼ºÀ» ºÐ¼®ÇÏ´Â µ¥ ÇÊ¿äÇÑ ±âÃʸ¦ Á¦°øÇÑ¡¦ |
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Electronic Spectral Properties of Cracac and Coacac ¿¹ºñº¸°í / 1. ½ÇÇèÀÌ·Ð 2. ½Ã¾à ¹× ±â±¸ 3. ½ÇÇè¹æ¹ý / 1. ½ÇÇèÀÌ·Ð ÀüÀÚ ½ºÆåÆ®·³ Ư¼º ºÐ¼®Àº ÈÇÕ¹°ÀÇ ±¸Á¶¿Í ÀüÀÚ »óŸ¦ ÀÌÇØÇÏ´Â µ¥ Áß¿äÇÑ ¿ªÇÒÀ» ÇÑ´Ù. Cr(acac)¿Í Co(acac)´Â °¢°¢ Å©·Ò°ú ÄÚ¹ßÆ® ÀÌ¿ÂÀ» Áß½ÉÀ¸·Î ÇÏ´Â ¾Æ¼¼Æ¿¾Æ¼¼Åä³×ÀÌÆ® º¹ÇÕü·Î, À̵é ÈÇÕ¹°ÀÇ ÀüÀÚ ½ºÆåÆ®·³Àº ±×µéÀÇ ÀüÀÚ ¹èÄ¡ ¹× ºÐÀÚ ´ëĪ¼º¡¦ |
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