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  • Synthesis, Electrochemistry and Luminescences of [Ru(bpy)3]2£«   (1 ÆäÀÌÁö)
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Synthesis, Electrochemistry and Luminescences of [Ru(bpy)3]2£«

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1. Abstract

2. Introduction

3. Experimental Section

4. Results and Discussion

5. Conclusions

6. References

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1. Abstract

[Ru(bpy)3]2+´Â ·çÅ×´½ À̿°ú Ȳ¸°°è ¸®°£µåÀÎ 2,2`-ºñÇǸ®µò(bpy)À¸·Î ±¸¼ºµÈ Âø¹°·Î, ±¤ÀüÀÚÀû Ư¼ºÀÌ ¶Ù¾î³ª°í ´Ù¾çÇÑ ÀÀ¿ë °¡´É¼ºÀ» Áö´Ñ Áß¿äÇÑ È­ÇÕ¹°ÀÌ´Ù. ÀÌ È­ÇÕ¹°Àº »çÁøÈ­ÇÐÀû ¹× Àü±âÈ­ÇÐÀû ¿¬±¸ÀÇ ÃÊÁ¡ÀÌ µÇ¸ç, ƯÈ÷ ¹ß±¤ ¼ºÁú·Î ÀÎÇØ »ý¹°ÀÇ·á ¹× ±¤ÀüÀÚ±â±â¿¡¼­ÀÇ È°¿ë¿¡ ´ëÇÑ °ü½ÉÀÌ Áõ°¡ÇÏ°í ÀÖ´Ù. º» ·¹Æ÷Æ®´Â [Ru(bpy)3]2+ÀÇ ÇÕ¼º ¹æ¹ý, Àü±âÈ­ÇÐÀû Ư¼º, ±×¸®°í ¹ß±¤ Ư¼ºÀ» Á¾ÇÕÀûÀ¸·Î ´Ù·é´Ù. ÇÕ¼º ºÎºÐ¿¡¼­´Â [Ru(bpy)3]2+ÀÇ Åë»óÀûÀÎ ÇÕ¼º ÀýÂ÷¸¦ ¼³¸íÇÑ´Ù. ÀϹÝÀûÀ¸·Î, ¸ÕÀú ·çÅ×´½ Àü±¸Ã¼¿Í ÀûÀýÇÑ ºñÇǸ®µò ¸®°£µå°¡ ¹ÝÀÀÇÏ¿© Âø¹°ÀÌ »ý¼ºµÈ´Ù. ÀÌ °úÁ¤¿¡¼­ ¹ÝÀÀ Á¶°Ç(¿Âµµ, ¹ÝÀÀ ½Ã°£, pH µî)°ú ¿ë¸ÅÀÇ ¿µÇâÀ» °í·ÁÇÏ¿© ÃÖÀûÀÇ ÇÕ¼º Á¶°ÇÀ» »êÃâÇÑ´Ù. ÇÕ¼º ÈÄ, »ý¼ºµÈ º¹ÇÕü´Â °íü »óÅ¿¡¼­ ºÐ¸®µÇ°í, Á¤Á¦ °úÁ¤À» ÅëÇØ ¼øµµ¸¦ ³ôÀδÙ. ºÐ±¤ÇÐÀû ºÐ¼® ±â¹ý°ú Å©·Î¸¶Åä±×·¡ÇǸ¦ ÅëÇØ »ý¼ºµÈ Âø¹°ÀÇ ¼øµµ¿Í ±¸Á¶¸¦ È®ÀÎÇÒ ¼ö ÀÖ´Ù. Àü±âÈ­ÇÐÀû Ư¼º ºÐ¼®¿¡¼­´Â [Ru(bpy)3]2+ÀÇ »êÈ­ ¹× ȯ¿ø ÀüÀ§, ±×¸®°í Àü±âÈ­ÇÐÀû ¹ÝÀÀ °æ·Î¸¦ Ž±¸ÇÑ´Ù. ÀÌ Âø¹°Àº Àü±Ø¿¡¼­ Àü±âÈ­ÇÐÀû È°¼ºµµ¸¦ º¸¿©ÁÖ¸ç, »çÀÌŬ¸¯ º¼Å¸¸ÞÆ®¸® ¹× ÀüÇÔÃà ºÐ¼®¡¦(»ý·«)


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Synthesis   Luminescences   Ru   bpy   2£«  


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