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Synthesis, Electrochemistry and Luminescences of [Ru(bpy)3]2£« (1)

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1. Abstract

2. Introduction

3. Experimental method

4. Results & Discussion

5. conclusion

6. Reference

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1. Abstract

[Ru(bpy)3]2+¿¡ ´ëÇÑ ¿¬±¸´Â ·çÅ×´½ Âø¹°ÀÇ ÇÕ¼º, Àü±âÈ­ÇÐÀû Ư¼º, ±×¸®°í ¹ß±¤ Ư¼ºÀ» Ž±¸ÇÏ´Â µ¥ ÁßÁ¡À» µÎ¾ú´Ù. ·çÅ×´½ Âø¹°Àº ±× µ¶Æ¯ÇÑ ÀüÀÚ ±¸Á¶·Î ÀÎÇØ ´Ù¾çÇÑ ÀÀ¿ë °¡´É¼ºÀ» Áö´Ï°í ÀÖÀ¸¸ç, ƯÈ÷ »ýÈ­ÇÐ °¨Áö, ž籤 º¯È¯, ±×¸®°í Çü±¤ À̹Ì¡ ºÐ¾ß¿¡¼­ ³ôÀº °ü½ÉÀ» ¹Þ°í ÀÖ´Ù. º» ¿¬±¸¿¡¼­´Â ·çÅ×´½ Âø¹°ÀÇ ´ëÇ¥ÀûÀÎ È­ÇÕ¹°ÀÎ [Ru(bpy)3]2+¸¦ Áß½ÉÀ¸·Î ÁøÇàÇÏ¿´´Ù. ÀÌ Âø¹°Àº µÎ °³ÀÇ 2,2¡¯-¾Æ¹Ì³ë Ç»¸°(2,2`-bipyridine, bpy) ¸®°£µå¸¦ ÅëÇØ ¾ÈÁ¤ÀûÀÌ°í ±¤ÇÐÀûÀ¸·Î À¯¿ëÇÑ ¼ºÁúÀ» ³ªÅ¸³½´Ù. ÇÕ¼º ºÎºÐ¿¡¼­´Â [Ru(bpy)3]2+ÀÇ ÇÕ¼ºÀ» À§ÇÑ Àü±¸Ã¼ ¹× ¹ÝÀÀ Á¶°ÇÀ» ¼¼¹ÐÈ÷ Á¶Á¤ÇÏ¿© ³ôÀº ¼øµµÀÇ Âø¹°À» ¾ò´Â °úÁ¤À» »ó¼¼È÷ »ìÆ캸¾Ò´Ù. ÀÌ´Â Âø¹°ÀÇ Àü±âÈ­ÇÐÀû Ư¼º°ú ¹ß±¤ ¼ºÁú¿¡ Á÷°áµÇ±â ¶§¹®ÀÌ´Ù. ÇÕ¼ºµÈ [Ru(bpy)3]2+ÀÇ Àü±âÈ­ÇÐÀû ºÐ¼®¿¡¼­´Â »çÀÌŬ¸¯ º¼Å¸¸ÞÆ®¸®¿Í °°Àº ±â¼úÀ» È°¿ëÇØ ÀüÀÚ À̵¿ Ư¼ºÀ» Æò°¡ÇÏ¿´´Ù. Àü±âÈ­ÇÐÀû ½ÇÇè °á°ú, [Ru(bpy)3]2+´Â ¾ÈÁ¤ÀûÀÎ »êÈ­ ¹× ȯ¿ø ¹ÝÀÀÀ» ³ªÅ¸³»¾î ÀÌ È­ÇÕ¹°ÀÌ Àü±Ø Ç¥¸é¿¡¼­ÀÇ ÀüÀÚ Àü´Þ ´É·ÂÀ» Áö´Ï°í ÀÖÀ½À» È®ÀÎÇÏ¿´´Ù. ÀÌ·¯ÇÑ Àü±âÈ­ÇÐÀû ºÐ¼®Àº Âø¹°ÀÇ ÀüÀÚ ±¸Á¶¿Í ¹ÝÀÀ ¸ÞÄ¿´ÏÁòÀ» ÀÌÇØ¡¦(»ý·«)


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Synthesis   Luminescences   Ru   bpy   2£«  


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