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  • Synthesis, Electrochemistry and Luminescence of [Ru(bpy)3]2£«   (1 ÆäÀÌÁö)
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  • Synthesis, Electrochemistry and Luminescence of [Ru(bpy)3]2£«   (1 ÆäÀÌÁö)
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Synthesis, Electrochemistry and Luminescence of [Ru(bpy)3]2£«

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ÆÄÀÏ : Synthesis, Electrochemistry and Luminescence of [R~.hwp   [Size : 18 Kbyte ]
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1. Abstract

2. Introduction

3. Experimental Section

4. Results and Discussion

5. Conclusions

6. References

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1. Abstract

[Ru(bpy)3]2+´Â Áß¿äÇÑ ±Ý¼Ó ÂøÈ­ÇÕ¹°·Î, Àü±âÈ­ÇÐÀû Ư¼º°ú ¹ß±¤ Ư¼ºÀÌ ¶Ù¾î³ª¸ç ´Ù¾çÇÑ ÀÀ¿ë °¡´É¼ºÀ» °¡Áö°í ÀÖ´Ù. ÀÌ Âø¹°Àº 2,2`-bipyridine(bpy) ¸®°£µå¿Í ·çÅ×´½ ±Ý¼Ó ÀÌ¿ÂÀ¸·Î ±¸¼ºµÇ¾î ÀÖÀ¸¸ç, ±× ±¸Á¶Àû Ư¼º ¶§¹®¿¡ ³Î¸® ¿¬±¸µÇ°í ÀÖ´Ù. º» ¿¬±¸¿¡¼­´Â [Ru(bpy)3]2+ÀÇ ÇÕ¼º ¹æ¹ý, Àü±âÈ­ÇÐÀû ¼ºÁú, ±×¸®°í ¹ß±¤ Ư¼ºÀ» ½ÉÃþÀûÀ¸·Î ºÐ¼®ÇÏ¿´´Ù. ÇÕ¼º ºÎºÐ¿¡¼­´Â ¸ÕÀú ±Ý¼Ó ¿°°ú ¸®°£µå¸¦ È¥ÇÕÇÏ¿© ·çÅ×´½ Âø¹°À» Á¦Á¶ÇÏ´Â ±âÃÊÀû Á¢±Ù ¹æ½ÄÀ» ¼Ò°³ÇÏ¿´´Ù. ÃÖÀûÈ­µÈ ÇÕ¼º Á¶°Ç ÇÏ¿¡ ³ôÀº ¼öÀ²°ú ¼øµµ¸¦ º¸ÀåÇÒ ¼ö ÀÖÀ¸¸ç, À̸¦ ÅëÇØ ¾ÈÁ¤ÀûÀÎ Âø¹°À» ¾òÀ» ¼ö ÀÖÀ½À» È®ÀÎÇÏ¿´´Ù. ÀÌ·¯ÇÑ ÇÕ¼º °úÁ¤Àº Âø¹°ÀÇ Àü±âÈ­ÇÐÀû ¹× ¹ß±¤ Ư¼º¿¡ °­·ÂÇÑ ¿µÇâÀ» ¹ÌÄ£´Ù. °ËÁõµÈ ÇÕ¼º ¹æ¹ý¿¡ µû¶ó »ý¼ºµÈ [Ru(bpy)3]2+ Âø¹°Àº ÈÄ¼Ó ½ÇÇè¿¡¼­ ±× Ư¼ºÀÌ Àß ³ªÅ¸³µ´Ù. Àü±âÈ­ÇÐÀû Ư¼º¿¡ ´ëÇØ, Àü±Ø¿¡¼­ÀÇ [Ru(bpy)3]2+ÀÇ »êÈ­¿Í ȯ¿ø ¹ÝÀÀ ¸ÞÄ¿´ÏÁòÀ» Á¶»çÇÏ¿´´Ù. Cyclic voltammetry¿Í °°Àº Àü±âÈ­ÇÐÀû ±â¹ýÀ» È°¿ëÇÏ¿© ÀÌ¿ÂÈ­ ¹ÝÀÀ°ú ÀüÀÚ À̵¿ °úÁ¤À» ºÐ¼®ÇÏ¿´´Ù. Àü±Ø¿¡¼­ÀÇ Àü±âÈ­ÇÐÀû ¹ÝÀÀÀº ÀÏÁ¤ÇÑ Àü¾Ð ¹üÀ§¿¡¼­ ¹Ýº¹ÀûÀ¸·Î ÀÌ·ç¾îÁö¸ç, ÀÌ´Â [Ru(bpy)3]2¡¦(»ý·«)


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Synthesis   Luminescence   Ru   bpy   2£«  


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